Comparative Study between Direct and Pseudomorphic Transformation of Rice Husk Ash into MFI-Type Zeolite.

نویسندگان

  • Hallah Ahmad Alyosef
  • Hans Roggendorf
  • Denise Schneider
  • Alexandra Inayat
  • Julia Welscher
  • Wilhelm Schwieger
  • Tom Münster
  • Gert Kloess
  • Suzan Ibrahim
  • Dirk Enke
چکیده

Pre-shaped mesoporous amorphous rice husk ash (RHA) and MCM-41 derived from RHA as a silica source were transformed into MFI-type zeolites using two different structure-directing agents. Tetrapropylammonium hydroxide (TPAOH) was utilized as an alkali source for silica dissolution and structure control during the direct transformation of RHA into zeolite. A monopropylamine (PA)-containing alkaline solution (NaOH) was used for the pseudomorphic transformation of RHA or MCM-41 into zeolite. The hydrothermal conversion of RHA or MCM-41 into MFI-type zeolites was investigated as a function of reaction time at 175 °C. With PA as template, the crystallization took place inside and on the outer surface of RHA or MCM-41 without losing the original shape of the initial silica sources, while TPAOH led to the formation of conventional MFI-type zeolite crystals due to the complete dissolution of RHA. The final products were characterized by X-ray diffraction, nitrogen adsorption, scanning electron microscopy, and optical emission spectroscopy.

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عنوان ژورنال:
  • Molecules

دوره 23 1  شماره 

صفحات  -

تاریخ انتشار 2017